With waste cooking oil, and animal fat derived biodiesel, we are actually making fuel out of a waste product, which does not compete with food at all. The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer reactor. This chemical reaction converts an ester vegetable oil or animal fat into a mixture of esters of the fatty acids that makes up the oil or fat. Faculty of mechanical engineering noushirvani university of technology, 47148, iran. Fat and oil share a basic structure, with a glycerine backbone supporting fatty acid chains. It is desirable as an alternative to petroleum fuel because it uses renewable resources that. Feb 18, 2014 an example of this is that all the frying oil used in restaurants is collected by authorized managers that go over 95% for the production of biodiesel and other to energy recovery. Production of biodiesel from waste cooking oil international. Biodiesel production from used cooking oil wholesale. Distillate that is produced by deodorization of palm oil ddpo is also a promising and cost effective feedstock 23. Production of biodiesel from waste cooking oils involves a fossil. Recovery of waste cooking oil used in the biodiesel.
Commercial biodiesel is sold as a blend with regular ultra low sulfur. Depending on the undesirable components especially free fatty acids and water, each catalyst have advantages and disadvantages. So, biodiesel produced from waste cooking oil is not. Energy analysis for biodiesel production from rapeseed oil h. Methanol is most commonly used in the commercial production of biodiesel, since it is generally less expensive than other alcohols, but ethanol prevails in regions such as brazil where it is less expensive than methanol. Having probability of contaminating environmental water, discarding of this waste cooking oil can be challenging hubera et al. It is alkali catalyzed reaction which involves waste cooking oil, methanol, and potassium hydroxide. Production of biodiesel from waste vegetable oil via km. The most common way is the production of biodiesel from waste cooking oil. Biodiesel is being produced from soybean oil, followed by animal fats and cottonseed oil, with palm and castor bean oil contributing in small portions. Its primary advantages deal with biodiesel being one of the most renewable fuels currently available and it is also nontoxic and. The biodiesel process used at rit was tailored for the residential cooking oil. Nonedible plant oil has been found to be promising crude oil for the production of biodiesel. The current technologies of biodiesel production are based on microemulsion 1, pyrolysis 2 and transesterification 3.
Biodiesel production technology august 2002january 2004. Moreover, these oils could be more expensive to use as fuel 7 and 8 compares the cost of biodiesel production based on the materials used. The use of waste cooking oil as biodiesel feedstock reduces the cost of biodiesel production. Hence, due to its abundance and low cost, waste cooking oil is going to be used as the raw material of biodiesel production. The study deals with the used cooking oil collection industry that lies at the intersection of two very promising sectors of the economy, the biofuels biodiesel industry and the waste management industry. Pdf production of biodiesel from used cooking oil find, read and cite all the research you need on researchgate. A comparative study of biodiesel production from waste cooking oil using sulfuric acid twostep and microwaveassisted transesterification onestep was carried out.
The components that support combustion in the oil are the basis for biodiesel. Introduction biodiesel refers to all kinds of alternative fuels derived from vegetable oils or animal fats. A twostep transesterification process was used to produce biodiesel alkyl ester from high free fatty acid ffa waste cooking oil. Thermoeconomic analysis of biodiesel production from used. The manufacture of biodiesel from the used vegetable oil uni kassel. This report is an overview of the biodiesel production process on a smallscale basis. Basics of biodiesel production biodiesel is an alternative fuel for diesel engines that is gaining attention in the united states. Life cycle assessment of biodiesel production from waste cooking oil in western australia abstract biodiesel derived from waste cooking oil wco is considered highly environmental sustainable since wco is a waste product which has been recycled to a transportation fuel in western australia. Biodiesel from used cooking oil uco is one of the most sustainable solutions to. While diesel engines can run off of normal vegetable and highly filtered animal fats, this requires engine modification. Chemically biodiesel is mono alkyl esters of long chain fatty acids derived from renewable feed stock like vegetable oils and animal fats.
However, the feedstock costs and scarcity of vegetable oil feedstock are always vital issues for the biodiesel production. Nov 10, 2012 japan has seen an increase in efforts to recycle used cooking oil a byproduct of supermarkets and cafeterias as biodiesel to use as a substitute for light diesel oil fuel for vehicles. Conversion of waste cooking oils into environmentally. A is the total peak area from the methyl ester in c6. Pdf production of biodiesel from waste cooking oil and. To minimize the biofuel cost, in recent days waste cooking oil was used as feedstock. The top countries of suppliers are austria, china, and indonesia, from which the percentage of used cooking oil for biodiesel supply is 1%, 64%, and 2% respectively. The transesterification process was implemented to extract the biodiesel, and this process was optimized and standardized by selecting three different parameters. Biodiesel is gaining more and more importance as an attractive fuel due to the depleting fossil fuel resources.
Preparation, characterization and application of zeolite. These sectors are heavily influenced by the guidelines and the incentives provided by the regulatory framework. Biodiesel is a combustible fuel that is biodegradable and made from vegetable oil or animal fat. Combining equations 3 and 4, the exergy cost can be calculated. Transformation of used cooking oil into biodiesel from waste to resource the frying process modifies vegetable oils from both a physical and a chemical point of view resulting in the creation of harmful compounds. Cooking oil consumption is high in indonesia, and there is no existing, systematic effort to collect and repurpose uco for other uses. Waste cooking oil is one of the alternatives for biodiesel process. Preparation, characterization and application of zeolitebased catalyst for production of biodiesel from waste cooking oil maryam hassani 1, ghasem d najafpour. Since the bse crisis european uco is classified as a waste that is no longer fit for human or animal. Moreover, large quantities of wco are dumped into landfills and rivers, causing pollution to the environment. Among the alternatives as a vegetal raw material to. By using ufo significant reduction in cost of biodiesel production can be achieved.
Since lipase catalysts are much expensive, the usage of lipase in biodiesel production is. Nov 25, 2019 biodiesel is a diesel fuel that is made by reacting vegetable oil cooking oil with other common chemicals. A qualitative analysis was initially performed using a gcxgctofms. Background the monthly biodiesel production report provides data on operations of the u. It can be seen that amongst the four materials such as palm oil, jatropha oil, soya bean oil and waste cooking oil, waste cooking oil can be seen as the. Sodium and potassium hydroxides are selected as catalyst.
Biodiesel production from refined used cooking oil using. A wide variety of used cooking oil for biodiesel options are available to you, there are 446 suppliers who sells used cooking oil for biodiesel on, mainly located in asia. The study focus on the physical and chemical properties of waste cooking oil wco, transesterification and production of biodiesel from wco. The conversion reached a value of above 50% in just 20 min.
The effects of methanol oil molar ratio, catalyst concentration, volumetric flow rates, and the presence of a cosolvent on the transesterification reaction were examined. The use of nonedible oil for biodiesel production compared with edible oil is very significant in developing countries because of the tremendous demand of edible oil as food and they are far too expensive to be used as fuel at present 5, 6. Students living in the campus eat their food in the mess or canteens where gallons of waste cooking oil are produced. The bad impacts of fossil fuel on the environment and climate change have been increased in the recent years. Small scale biodiesel production feasibility report. Biodiesel production from waste cooking oil carlos a. Waste cooking oils should be used for biodiesel production to turn waste into energy. These sectors are heavily influenced by the guidelines and. Here is the basic procedure for making biodiesel fuel. Alkali transesterification procedure is used for the conversion.
Free fatty acids will increase the time required for heating vegetable oil. Biodiesel from waste cooking oil wco can reduce the cost of biodiesel production since the feedstock costs constitutes approximately 7095% of the overall cost of biodiesel production 6. This study focuses on the use of waste cooking oil wco as the main feedstock for hydrotreatment to evaluate the effect of temperature on the product hydrocarbon composition. Biodiesel is made by transesterification of vegetable oil. Astm international originally known as the american society for testing and. Water impedes the biodiesel reaction resulting in only partial conversion of the oil to biodiesel. Energy analysis for biodiesel production from rapeseed oil. Biodiesel from used cooking oil future potential gold. The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the volumetric flow rates of. Although biodiesel cannot entirely replace petroleumbased diesel fuel, there are at. The main resource for biodiesel production can be any vegetable oil may be edible or nonedible oils, waste cooking oil, beef tallows etc. The thrust of this work is the design and building of a compact tabletop chemical reactor for carrying out transesterification of used cooking oil for the production of biodiesel.
The work concludes with a series of experiments for obtention of biodiesel from corn oil. An improvement in biodiesel production from waste cooking oil by. Apr 19, 2017 in this study, biodiesel was produced using waste cooking oil that was discarded as a waste in the environment. The use of enzymes has also been employed in the biodiesel production with reports of high performance in esters from used cooking oil. My project deals with the synthesis of biodiesel from palm oil a cheaper vegetable oil of the market.
The biodiesel process used at rit was tailored for the residential cooking oil which tends to be high in water content. A wide variety of biodiesel production from used cooking oil options are available to you, such as vehicles, heating oil, and aviation. Biodiesel is an alternative diesel fuel produced from a catalyzed reaction of the triglycerides in the oil or fat with a simple monohydric alcohol methanol. Pdf cost analysis for biodiesel production from waste. The dominant biodiesel feedstock for biodiesel consumed in the uk is used cooking oil uco, defined as the purified oils and fats of plant and animal origin that have been used to cook food. Biodiesel production an overview sciencedirect topics. Biodiesel is a form of diesel fuel derived from plants or animals and consisting of longchain. Feedstocks there were a total of 1,042 million pounds of feedstocks used to produce biodiesel in january 2020. Unlike the vegetable and waste oils used to fuel converted diesel engines. Catalysts used in this process are usually acids, base, and lipase. Sodium and potassium hydroxides are selected as catalyst 2 vegetable oils 2. Process to produce biodiesel using jatropha curcas oil jco.
Production of biodiesel from vegetable oil by transesterification process using continous enzymatic reactor advisors. Biodiesel production from jatropha and waste cooking oils. The reaction was carried out at 15 min, 30 min, 60 min, 90 min, and 120 min to evaluate the effect of reaction time on the yield of fatty acid methyl ester fame. The potential economic, heath, and greenhouse gas benefits. Used frying oil is far less expensive than refined vegetable oils and therefore has. The aim of the present study was to evaluate and recovery of cooking oil used by the biodiesel production. Biodiesel may be used in any diesel automotive engine in its pure form or blended with petroleumbased diesel.
Conversion of waste cooking oil to biodiesel 11 biodiesel feedstock competes with the use of land for food production. The btech 40 produces 40l biodiesel from 40l used cooking oil per cycle of 10 to 12 hours. Among them, vegetable oils are now being used as a sustainable commercial feedstock. Paper open access aspen hysys simulation for biodiesel. Cooking oil use for biodiesel production in colombia 2019. Transesterification and production of biodiesel from waste. The use of al kaline or acid catalysts in homogenous catalytic system cause difficulties in process such as removing of catalysts, collection of biodiesel. Biodiesel production from used edible oils commonly known as waste cooking oil, wco had more economic feasibility compared to fresh plant oils. Harmful emissions are dramatically reduced and biodiesel lubricates more efficiently than fossil diesel fuel, so it has the potential to increase engine life. Biodiesel is a renewable, cleanburning fuel derived from vegetable oil, among other oils, and can be mixed with any kind of. International journal of materials science and engineering.
Production of biodiesel from used cooking oil free download as powerpoint presentation. Before we get into what biodiesel equipment is needed, it would be good to quickly explain how and why biodiesel is made. Biodiesel production from waste cooking oils sciencedirect. Chemically biodiesel is mono alkyl esters of long chain fatty acids derived from renewable feed stock like vegetable oils. Implications of imported used cooking oil uco as a. Business plan for the development of a used cooking oil. This paper aims at the assessment of the methods of production of biodiesel from different types of used cooking oil. Biodiesel can be obtained from oils such as cassava oil, palm oil, and corn oil, but the use of these sources for the production of biodiesel would have a negative impact on food supplies 8. Biodiesel is completely biodegradable and far safer to store than fossil diesel. The government announced last week that staterun oil marketing companies will for three years procure all the biodiesel produced from used cooking oil.
The depletion of fossil fuel forces the world to look for alternative ways for energy production. Nov 06, 2016 it is prepared from waste vegetable oils and animal fats by transesterification process. Production of biodiesel from corn oil and ethanol by. However, in indonesia, palm oil is the main feedstock for biodiesel production. Production of biodiesel from vegetable oils article pdf available in grasas y aceites 591 march 2008 with 27,509 reads how we measure reads.
This paper presents a detailed cost analysis for a biodiesel plant with. No modifications are required, and the result is a lessexpensive, renewable, cleanburning fuel. Creating fuel from used cooking oil farmers weekly. The aim of study is to produce the synthesis of biodiesel from waste cooking oil.
Pdf production of biodiesel from cooking oil using cao catalyst. Jan 24, 2020 how to prepare used cooking oil for biodiesel. Meanwhile, the production of biodiesel from different feed stock is shown in fig. However, the time and energy spent to create biodiesel can make it seem to be more expensive than readily available diesel. Most vegetable oil can be converted into biodiesel but cost of the vegetable oil feedstock is now a factor in the least cost production of biodiesel. The production of biodiesel, c from refined used cooking oil was carried out by analyzing the gc chromatograms as shown in fig. Uco biodiesel production in the indonesian context and assess the total national ghg benefits from using uco for biodiesel.
Optimized biodiesel production from waste cooking oil wco. This study investigated the use of km micromixer in the production of biodiesel from waste vegetable oil. Biodiesel production from waste cooking oil is found to be economically feasible method. Biodiesel is produced from vegetable oils or animal fats and an alcohol, through a transesteri. Researches into the productive chain of this type of biofuel were performed in brazil while several scientific studies approaching processes of pretreatment and transesterification of waste cooking oil were analyzed with their possible variations. Life cycle assessment of biodiesel production from waste. Pdf biodiesel production from waste cooking oil researchgate. Given the required technology and the huge amount of waste cooking oil generated in hong kong, mass production of biodiesel is feasible. Pdf waste cooking oil to biodiesel fuel ahmad j al. Lipase catalysis for transesterification produces biodiesel using coconut oil as main raw material source. The three esters are released from the glycerol skeleton and combine with the alcohol to yield fatty acid. The properties of the feedstock were determined using standard astm methods. Third, biodiesel is a renewable and clean burning energy source. Biodiesel, a realistic fuel alternative for diesel engines springer2008.
Calcium oxide cao was selected as the best catalyst. Pdf hydrotreating of waste cooking oil for biodiesel. Moreover, the price of edible plant and vegetable oils is usually higher than petro diesel. The property of biodiesel depends on the type of fresh cooking oil used 10. Sierra national university of colombia, colombia 1. This thesis includes a study regarding production of biodiesel from vegetable oils. Colombias biodiesel production is derived from palm oil and, in smaller. Production of biodiesel from used cooking oil biodiesel. Biodiesel production from waste cooking oil wco provides an alternative energy means of producing liquid fuels from biomass for various uses. Biobot 20 countertop diesel processor converts waste cooking. How modi govt will turn used cooking oil into biodiesel to. Biodiesel made from vegetable oils containing 10% used cooking oil was the most applicable for blending. The biobot 20 tabletop diesel processor converts waste vegetable oil into biodiesel 3 3 ukbased biobot has introduced a simple chemical reactor for converting used kitchen oils into biodiesel.
Paradoxically, the higher cost of solid vegetable oil affects the production cost of biodiesel. Recent strategy of biodiesel production from waste cooking. The production of biodiesel from waste vegetable oil offers a triplefacet solution. Biodiesel handling and use guide, fourth edition pdf. With soy biodiesel, the food part of the bean is still used for food, so soy biodiesel actually encourages more food production, not less. The transesterification process was carried out by mixing koh 1% of oil weight with methanol ratio of methanol.
In this study, production of biodiesel from cooking oil co was carried out via transesterification method. The brazilian national program for production and use of biodiesel pnpb launched 2003 created a demand of biodiesel and stimulated the biodiesel production. Production of biodiesel was involved transesterification process that implicated the reaction between used cooking oil and methanol with aid of koh. The concept of using vegetable oil for fuel has been around, as long as the diesel engine. Used cooking oil from restaurants can be recycled and turned into biodiesel with the help of a licensed grease collection service through rendering processing and refining technologies at treatment plants. Different sources of raw material used for the production of biodiesel are shown in figure 3. All vegetable oils can be used to produce biodiesel, particularly from castor. Thus 4 litres of biodiesel was produced from 4 litres of used vegetable oil and 800mls of sodium methoxide. Palm oil and its use for production of biodiesel are focused.
Infact, using waste vegetable oil reduces the need for biodieselproducing crops and the competition with food3,5,14. It is desirable as an alternative to petroleum fuel because it uses renewable resources that are less damaging to the environment to produce and emit. Soybean oil remained the largest biodiesel feedstock during january 2020 with 521 million pounds consumed. Utilization of waste cooking oil for biodiesel production. In 2018, colombias biodiesel production amounted to 627 million liters, an increase of 15 percent in comparison to the previous year. It is prepared from waste vegetable oils and animal fats by transesterification process. While some of collected uco is refined into biodiesel, the rest is exported, reused as. Nov 21, 20 preparation of biodiesel for preparation of biodiesel in the lab alkali catalyzed transesterification is to be used. Biodiesel production from waste cooking oil intechopen. Cost of biodiesel produced from virgin vegetable oil through transesterification is higher than that of fossil fuel, because of high raw material cost. However, large amount of waste cooking oil is produced from restaurants, eatering establishments and food industries, etc, every year. Biodiesel equipmentwhat is needed to make biodiesel. Commercial grades are represented by a number following a b letter. It is clear that the soybean oil is in the first position, while palm oil is in second position.
This is actually a great project to start on if you are a college student where used cooking oil is in abundance. About 58% of these are biodiesel, 28% are machine oil purifier, and 1% are sunflower oil. The use of cooking oil for biodiesel production in the country is forecasted to remain stable at 30 thousand tons in 2019. Technically, the methods for the production of biodiesel from used cooking oil do not differ from conventional transesterification processes using alkaline, acid and enzymatic catalysts. Lipase catalysis for transesterification produces biodiesel.
125 442 681 1442 764 918 1254 661 880 1126 176 508 1153 782 1405 1482 369 1237 677 481 678 1428 1227 817 336 1246 1244 406 1007 887 1387 1189 251 464 662 566 604 668